A modified DNA genetic algorithm for parameter estimation of the 2-Chlorophenol oxidation in supercritical water

Based on the mechanism of biological DNA genetic information and evolution, a modified DNA genetic algorithm (MDNA-GA) is proposed to estimate the kinetic parameters of the 2-Chlorophenol oxidation in supercritical water. In this approach, DNA encoding method, choose crossover operator and frame-shift mutation operator inspired by the biological DNA are developed for improving the global searching ability. Besides, an adaptive mutation probability which can be adjusted automatically according to the diversity of population is also adopted. A local search method is used to explore the search space to accelerate the convergence towards global optimum. The performance of MDNA-GA in typical benchmark functions and kinetic parameter estimation is studied and compared with RNA-GA. The experimental results demonstrate that the proposed algorithm can overcome premature convergence and yield the global optimum with high efficiency.