Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
170718 | Comptes Rendus Chimie | 2013 | 5 Pages |
Abstract
Organocatalyst trityl chloride (Ph3CCl), by in situ formation of trityl carbocation with inherent instability, efficiently promotes the cross-aldol condensation reaction between cycloalkanones and arylaldehydes in solvent-free and homogeneous media to afford α,α′-bis(arylidene)cycloalkanones in high yields. Moreover, an attractive and plausible mechanism based on observations and the literature is proposed for the reaction.
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Related Topics
Physical Sciences and Engineering
Chemical Engineering
Chemical Engineering (General)
Authors
Abdolkarim Zare, Maria Merajoddin, Alireza Hasaninejad, Ahmad Reza Moosavi-Zare, Vahid Khakyzadeh,