Article ID Journal Published Year Pages File Type
170901 Comptes Rendus Chimie 2012 5 Pages PDF
Abstract

The regispecific synthesis of pyrazolines has been accomplished through the 1,3-dipolar cycloaddition of 2-diazopropane to pyridazine-3,6-dione derivatives. A convenient and inexpensive ultrasound-assisted preparation of bicyclo-cyclopropanes in a completely stereoselective manner in almost quantitative yields has been realized. The highly stereoselective extrusion of nitrogen suggests a concerted mechanism.

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Physical Sciences and Engineering Chemical Engineering Chemical Engineering (General)
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