Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
171174 | Comptes Rendus Chimie | 2010 | 18 Pages |
Abstract
Allyl complexes based on group IIIb metals (Sc, Y, La) and lanthanides are reviewed. The diversity, synthesis, and main structural and reactivity features of discrete, well-defined homoleptic and pseudo-homoleptic neutral, anionic and cationic bis-, tris- and tetra(allyl)-lanthanide complexes, as well as heteroleptic allyl-lanthanidocenes and allyl-lanthanide complexes supported by non-Cp ligands are covered. Brief comments on the catalytic performances of some key compounds in polymerization processes are also provided.
Related Topics
Physical Sciences and Engineering
Chemical Engineering
Chemical Engineering (General)
Authors
Jean-François Carpentier, Sophie M. Guillaume, Evgueni Kirillov, Yann Sarazin,