| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 171193 | Comptes Rendus Chimie | 2010 | 9 Pages |
Abstract
The diamantane functionalized triazacyclononane ligand (DiaArOH)3tacn (L3) has been synthesized and the reactivity of its U(III) metallated product [((DiaArO)3tacn)U] (1) has been explored. Complex 1 promotes dichloromethane and azidotrimethylsilane activation to generate U(IV) complex [((DiaArO)3tacn)U(Cl)] (2) and U(V) complex [((DiaArO)3tacn)U(NTMS)] (3), respectively. Spectroscopic investigations of complexes 1, 2, and 3 will be discussed, along with molecular structures where possible.
Related Topics
Physical Sciences and Engineering
Chemical Engineering
Chemical Engineering (General)
Authors
Oanh P. Lam, Frank W. Heinemann, Karsten Meyer,