| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1712104 | Biosystems Engineering | 2009 | 7 Pages |
A set of experiments was carried out to investigate the chemical oxidation of 5-O-caffeoylquinic acid (5-CQA) in the temperature range of 96–188 °C. A batch cylindrical reactor made of glass and operated at isothermal conditions was used in the experiments. The decay of 5-CQA concentrations was monitored with a spectrophotometer at 323 nm by involving a coefficient of molar absorptivity equal to 2.7 × 104 ± 0.3 × 104 M−1 cm−1 for 5-CQA. A simplified kinetic model suggested by assuming an irreversible homogeneous pseudo-first order reaction was able to describe the effect of reaction time on 5-CQA concentrations. The influence of temperature on reaction rates was correctly reproduced with the Arrhenius expression with an activation energy and a natural logarithm of the frequency factor close to 42185 ± 7399 J mol−1 and 3 ± 2, respectively. The reliability of the entire experimental and modelling procedure was confirmed by comparisons between calculated and experimental dimensionless 5-CQA concentrations reported in the literature. Uncertainty analysis was performed to check the consistency of the estimated parameters and experimental data. Simulations indicate high rates of oxidation 5-CQA in the mate industry at temperatures and residence times typically found in the stages of enzymatic deactivation and drying.
