Article ID Journal Published Year Pages File Type
171285 Comptes Rendus Chimie 2010 5 Pages PDF
Abstract

The CuCl/NaOt-Bu/BINAP system was found to efficiently catalyze the hydrosilylation of aryl alkyl ketones with excellent enantioselectivities by using phenyl methyl silane as a stoichiometric hydride source. High enantiomeric excesses (up to 97%) and excellent yields (up to 99%) were obtained.

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Physical Sciences and Engineering Chemical Engineering Chemical Engineering (General)
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Enantioselective hydrosilylation of prochiral ketones catalyzed by chiral BINAP-copper(I) complexes
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