Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
171285 | Comptes Rendus Chimie | 2010 | 5 Pages |
Abstract
The CuCl/NaOt-Bu/BINAP system was found to efficiently catalyze the hydrosilylation of aryl alkyl ketones with excellent enantioselectivities by using phenyl methyl silane as a stoichiometric hydride source. High enantiomeric excesses (up to 97%) and excellent yields (up to 99%) were obtained.
Related Topics
Physical Sciences and Engineering
Chemical Engineering
Chemical Engineering (General)
Authors
Jean-Thomas Issenhuth, Samuel Dagorne, Stéphane Bellemin-Laponnaz,