Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
171405 | Comptes Rendus Chimie | 2009 | 10 Pages |
Abstract
A short series of dehydrobenzothieno- and dehydropyridothieno[15]annulene ([15]DBTA and [15]DPTA) hybrids were assembled from thiophene, acetylene, and benzene/pyridine components. The molecules were constructed in a convergent manner and their properties examined optically, electrochemically, and thermally. In addition to lowered energy of electronic transitions of the 15-membered macrocycles, their emissive properties are discussed. The observed trends correspond with previously reported [14]annulenes, and are further rationalized using DFT (B3LYP/6-311Gāā) calculations.
Related Topics
Physical Sciences and Engineering
Chemical Engineering
Chemical Engineering (General)
Authors
Matthew J. O'Connor, Robert B. Yelle, Thomas M. Linz, Michael M. Haley,