Article ID Journal Published Year Pages File Type
171661 Comptes Rendus Chimie 2007 8 Pages PDF
Abstract

C3-symmetric triphenoxymethane platforms were substituted with carbamoylmethylphosphine sulfide arms and these tris-CMPS compounds were evaluated as extractants for f-element metal ions from 1 M nitric acid solution. Their properties were compared to the carbamoylmethylphosphine oxide derivatives on the same triphenoxymethane platform (tris-CMPO). The terbium complex of tris-CMPS was crystallized and examined via X-ray structural analysis to provide valuable insight into the binding properties of the soft tripodal chelate.

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Physical Sciences and Engineering Chemical Engineering Chemical Engineering (General)
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