Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
171661 | Comptes Rendus Chimie | 2007 | 8 Pages |
Abstract
C3-symmetric triphenoxymethane platforms were substituted with carbamoylmethylphosphine sulfide arms and these tris-CMPS compounds were evaluated as extractants for f-element metal ions from 1 M nitric acid solution. Their properties were compared to the carbamoylmethylphosphine oxide derivatives on the same triphenoxymethane platform (tris-CMPO). The terbium complex of tris-CMPS was crystallized and examined via X-ray structural analysis to provide valuable insight into the binding properties of the soft tripodal chelate.
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Physical Sciences and Engineering
Chemical Engineering
Chemical Engineering (General)
Authors
Kornelia Matloka, Ajay K. Sah, Priya Srinivasan, Michael J. Scott,