| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 176177 | Dyes and Pigments | 2014 | 9 Pages |
•A series of chromophores were synthesized with acceptors of pyridinylbenzothiadiazole.•The chromophores present two-photon absorption cross-section from 121 to 254 GM.•The two-photon fluorescence quenching to the metal ions is sensitive.•Showing potential application in heavy metal detecting or environmental sensor.
New two-photon up-conversion fluorescence (TPF) sensors, containing triphenylamine or carbazole as donor (D) and flanked pyridinylbenzothiadiazole as acceptor (A) to form D–π–An(n=1, 2 or 3) architecture, were synthesized and characterized. The investigation correlated molecular structure (acceptor number) with linear absorption, one-photon fluorescence (OPF) and two-photon fluorescence (TPF) detecting Cu2+, Ni2+, Hg2+ and Ag+ was carried out. Sensors containing more acceptor groups were found to exhibit greater sensitivity to both absorption and fluorescence detection. A comparison between OPF and TPF responses to the given metal ion (Cu2+) showed that the sensitivity of TPF quenching is larger than that of OPF quenching. This strongly supports the idea that pyridinylbenzothiadiazole-based chromophores with more acceptor groups possess potential application as two-photon up-conversion sensors.
