Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
176325 | Dyes and Pigments | 2014 | 6 Pages |
•As a versitle platform for phosphorescent chemosensors, bis (benzylic amine) derivative 6 was synthesized.•A phosphorescent chemosensor 1 displayed a selective phosphorescence enhancement with H2PO4−.•A new iridium complex 2 is reported as a first chiral phosphorescent chemosensor for amino acids.
As a versatile platform for phosphorescent chemosensors, bis(benzylic amine) derivative 6 was synthesized. Two urea groups could be readily introduced for phosphorescent chemosensor 1. A preorganized binding pocket could induce a selective phosphorescence enhancement with H2PO4−. A new iridium complex 2 bearing two thiourea groups as well as glucopyranosyl chiral barriers is reported as a first chiral phosphorescent chemosensor for amino acids.
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