Article ID Journal Published Year Pages File Type
176478 Dyes and Pigments 2013 10 Pages PDF
Abstract

•Two new perylene diimide molecules were synthesized.•PDI-2 and PDI-3 were used as n-type components in solar cells.•Solar cells with P3HT exhibit efficiencies approaching 1%.

Two new perylene diimide molecules, 1, 7-bis(1-naphtyl)-N,N′-bis-(10-nonadecyl)-perylene-3,4,9,10-bis (dicarboximide) PDI-2 and 1,7-bis(5-acenaphtenyl)-N,N′-bis-(10-nonadecyl)-perylene-3,4,9,10-bis(dicarboximide) PDI-3 have been synthesized and used as acceptor components in P3HT/PDI bulk heterojunction solar cells. The introduction of fused aromatic rings into the bay positions of the perylene core creates a stong steric hindrance, twisting the perylene plane with a direct consequence on the π–π intramolecular interactions between the adjacent PDIs. All these features contribute to the reduction of molecular aggregation in the solid state, with a strong influence on the performances of P3HT/PDI photovoltaic devices.

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Physical Sciences and Engineering Chemical Engineering Chemical Engineering (General)
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