Article ID Journal Published Year Pages File Type
176587 Dyes and Pigments 2013 6 Pages PDF
Abstract

A novel ratiometric fluorescent sensor bearing two benzimidazole groups has been synthesized. The sensor showed a ratiometric fluorescence response with an enhancement of the ratios of emission intensities at 443 and 378 nm from 0.17 to 3.21 for Cr3+. The ratios of emission intensities at 443 and 380 nm were enhanced from 0.40 to 2.09 for Fe3+. Fe3+ revealed significant adsorption in the UV–vis region, which can be used to discriminate Cr3+ and Fe3+. Detection limits of the method for Cr3+ and Fe3+ were 25 μM and 2 μM, respectively. In addition, the sensor showed good selectivity to Cr3+ and Fe3+ over other metal ions.

Related Topics
Physical Sciences and Engineering Chemical Engineering Chemical Engineering (General)
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