Article ID Journal Published Year Pages File Type
176643 Dyes and Pigments 2012 7 Pages PDF
Abstract

We present the design, synthesis, characterization and spectral studies for a new Zn (II) and Fe (II) selective fluorescent probe, 4,4-Difluoro-8-{3-[(4-phenoxy-dipyrromethene)propoxy]}-4-bora-3a,4a-diazaindacene (DPYBODPY). DPBODPY consists of a terminal fluorophore and a selective ligand and was designed to detect significant changes in absorbance and/or fluorescence on metal ion binding. The fluorophore is based on the Bodipy unit due to its excellent photophysical properties, while the dipyrrin unit has specific recognition abilities for Fe2+ and Zn2+ ions. The combination of these two structures is optimised to achieve significant spectral changes in the presence of Fe2+ and Zn2+ ions.

► A novel fluorescent sensor was synthesized and characterised. ► The ability of the new sensor to discriminate between metal cations was investigated. ► The novel sensor was shown to selectively recognize Fe (II) and Zn (II) cations. ► Stoichiometry and binding constants for metal complexes of the sensor were determined. ► Competition experiments indicate the sensor can discriminate between mixtures of metal ions.

Related Topics
Physical Sciences and Engineering Chemical Engineering Chemical Engineering (General)
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