Article ID Journal Published Year Pages File Type
176783 Dyes and Pigments 2012 7 Pages PDF
Abstract

Phosphorescence has seldom been observed in purely organic dyes in the solution at room temperature. We herein report efficient phosphorescence in the solution from (E)-3-benzylideneimidazo[1,2-a]pyridin-2(3H)-one and its derivatives. This opens up a new class of purely organic dyes to applications in the phosphor design. In the solid state, the ordered columnar stacking arrangements, intermolecular close contacts, and lateral intermolecular hydrogen bonding interactions between neighboring columns make these luminogenic molecules highly phosphorescent at room temperature, and lead to phosphorescent color changes (from yellow in the solution to aurantiacus–red in the solid state). Here, using these luminogenic molecules, a series of new purely organic phosphors are color-tuned to emit yellow, aurantiacus, orange, nacarat and red in the solid state, which are promising candidates for potential applications in organic light-emitting diodes for display.

Graphical abstractThe new organic dyes based on (E)-3-benzylideneimidazo[1,2-a]pyridin-2(3H)-one display phosphorescence in solution and yellow to red phosphorescent colors in the solid state.Figure optionsDownload full-size imageDownload as PowerPoint slideHighlights► (E)-3-benzylideneimidazo[1,2-a]pyridin-2(3H)-one derivatives. ► A new class of phosphorescent dyes was obtained via one-pot synthesis method. ► These dyes exhibit efficient room-temperature phosphorescence in solution. ► In the solid, some dyes display stacking-induced phosphorescent color changes. ► The phosphorescence nature is further supported by the long decay lifetimes.

Related Topics
Physical Sciences and Engineering Chemical Engineering Chemical Engineering (General)
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