Article ID Journal Published Year Pages File Type
177160 Dyes and Pigments 2011 5 Pages PDF
Abstract

A bis-rhodamine based fluorescent chemosensor for naked-eye detection of Cu2+ with enhanced sensitivity as compared to mono-rhodamine derivative has been synthesized, and its selectivity for Cu2+ in the presence of other competitive metal ions (Li+, Na+, K+, Cs+, Mg2+, Ca2+, Sr2+, Cr3+, Mn2+, Fe2+, Fe3+, Co2+, Ni2+, Zn2+, Cd2+, Hg2+, and Pb2+), and application in bio-imaging are demonstrated.

► The sensitivity and selectivity for Cu2+ ions of two chemosensors compared. ► The structure of Cu2+-bis-rhodamine complex has been determined. ► NMR, EPR, UV, Fluorescence and energy minimization studies confirm the structure. ► The sensor is stable over a broad range of pH. ► The chemosensor is useful for the imaging of bacteria exposed to Cu2+ ions ion.

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Physical Sciences and Engineering Chemical Engineering Chemical Engineering (General)
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