Article ID Journal Published Year Pages File Type
177272 Dyes and Pigments 2010 8 Pages PDF
Abstract

Heteroleptic cyclometalated platinum (II) complexes bearing diarylamino-functionalized 1-phenylisoquinoline derivatives as primary ligand and acetyl acetonate as ancillary ligand were prepared and characterized. Single-crystal X-ray diffraction revealed that platinum (II) (4-(isoquinolin-1-yl)-N,N-diphenylbenzenamine-N,C2′) (2,4-pentanedionato-O,O) displayed square planar molecular geometry with Pt···Pt separation of 6.328 and 6.275 Å. The platinum (II) complexes displayed good thermal and morphological stability, as well as intense ligand-centered fluorescence and π–π* phosphorescence at 298 K, as well as strong phosphorescence at 77 K in dichloromethane. The double-layer polymer light-emitting diodes using 6a as emitters and a blend of poly(9,9-dioctylfluorene) and 2-(4-tert-butyl)-phenyl-5-biphenyl-1,3,4-oxadiazole as host matrix exhibit best performance with the maximum external quantum efficiency as high as 8.6% at 0.66 mA cm–2.

Related Topics
Physical Sciences and Engineering Chemical Engineering Chemical Engineering (General)
Authors
, , , , , , , ,