Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
177302 | Dyes and Pigments | 2011 | 11 Pages |
Natural anthraquinonoid dyes (alizarin and purpurin) were used as platform chemicals to synthesise sustainable alternatives to existing synthetic dyes by alkylation of hydroxy groups in the 1- and 2-positions. In comparison with the parent compounds, the derivatised dyes were insensitive to pH change, insoluble in alkali and the λmax for the mono-alkylated derivatives was unchanged and that of the bis-alkylated derivatives was reduced by 53–54 nm. Melting points decreased with derivatisation as the ability of the dyes to form inter-molecular interactions decreased. Dye exhaustion and colour strength values for dyeings on PET were relatively high for the parent and mono-alkylated derivatives and lower for the larger bis-alkylated derivatives. Mono-alkylation with methyl-4-butanoate groups improved the dyeing properties of the dyes on PLA. All dyeings displayed excellent wash fastness and the light fastness was improved in the case of the mono-alkylated derivatives owing to the removal of the photo-sensitive 2-hydroxy group.