Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
177767 | Dyes and Pigments | 2009 | 5 Pages |
Abstract
Two novel fluorescent pH probes based on 4,4-difluoro-4-bora-3a,4a-diaza-s-indacene dyes were configured as a “fluorophore-spacer-receptor” system. Their absorption and fluorescence properties were investigated in various solvents; in aqueous solution, based on their photo-induced electron transfer, the probes exhibited 3-fold (pH 8.70–4.93) and 14-fold (pH 9.02–3.29) fluorescence enhancement upon increase in the acidity of the solution, respectively. The probes can be used as fluorescent pH probes which are excitable with visible light; the pKa values of the probes were determined from the fluorescence changes.
Related Topics
Physical Sciences and Engineering
Chemical Engineering
Chemical Engineering (General)
Authors
Maozhong Tian, Xiaojun Peng, Feng Feng, Shuangming Meng, Jiangli Fan, Shiguo Sun,