Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
178131 | Dyes and Pigments | 2008 | 5 Pages |
Abstract
A tetranitrile monomer was synthesized by nucleophilic aromatic substitution of pyridine-2,6-diyldimethanol onto 4-nitrophthalonitrile. A metal-free phthalocyanine polymer was prepared by the reaction of a tetranitrile monomer with 4,4′-[pyridine-2,6-diylbis(methyleneoxy)]diphthalonitrile in DMAE. Ni(II), Co(II), Cu(I)-phthalocyanine polymers were prepared by reaction of the tetranitrile compound with the chlorides of Ni(II), Co(II) and Cu(I) in DMAE. The Zn(II)-phthalocyanine polymer was prepared by reaction of the tetranitrile compound with the acetates of Zn(II) in DMAE. The new compounds were characterized by a combination of IR, 1H NMR, 13C NMR, UV–vis, elemental analysis and MS spectral data.
Related Topics
Physical Sciences and Engineering
Chemical Engineering
Chemical Engineering (General)
Authors
Halit Kantekin, Zekeriya Bıyıklıoğlu,