New analysis of the Mössbauer spectra of olivine basalt rocks from Gusev crater on Mars

The Mars Exploration Rover, Spirit, landed on 4 January 2004, in a lava field in Gusev crater on Mars. Samples interpreted as olivine basalt have been investigated with Mössbauer spectroscopy and chemically with Alpha-particle-X-ray spectrometry (APXS).In this contribution we present the results of a new analysis of the Mössbauer spectra of selected rock targets in Gusev crater. The results show that the rock surfaces investigated are inhomogeneous, and show strong enhancement of olivine in the surface layer. By subtraction of the surface signal to obtain the spectrum of the true interior of the rock samples, the measurements show the usual correlation between olivine and iron oxides of olivine basalt.It is argued that the compositional changes observed are related to high temperature oxidation of the rocks, probably during solidification, a process known to lead to anomalously magnetic rocks. The rock Mazatzal is discussed in some detail, and it is suggested that the surface is covered with deposits rich in ferric iron rather than these ferric phases being due to oxidation of the rock. The fact that all the surfaces in this investigation show this same pattern, suggests that the dominating erosion of the surface layer of basaltic rocks at Gusev crater has been mechanical rather than chemical.