Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
178233 | Dyes and Pigments | 2007 | 5 Pages |
Abstract
A new metal-free and metallophthalocyanine carrying four 1,1′-biphenyl crown ether units on peripheral positions have been synthesized. Metal-free phthalocyanine was prepared by the reaction of 2,3-(4′,5′-dicyanobenzo)-11,12:13,14-di(1′,2′-biphenyl)-1,4,7,10,15,18-hexaoxacycloeicosa-2,11,13-triene with dry 2-(N,N-dimethylamino)ethanol under reflux. Metal derivative of phthalocyanine was also synthesized by the anhydrous NiCl2 and metal-free phthalocyanine in dry quinoline under reflux. The target symmetrical phthalocyanines were separated by column chromatography and characterized by elemental analysis, 1H, 13C NMR, IR, UV–visible and FAB mass spectroscopies.
Related Topics
Physical Sciences and Engineering
Chemical Engineering
Chemical Engineering (General)
Authors
Halit Kantekin, Murat Rakap, Yaşar Gök, Halil Zeki Şahinbaş,