Article ID Journal Published Year Pages File Type
1785088 Infrared Physics & Technology 2006 6 Pages PDF
Abstract

High-pressure infrared (IR) absorption study of phase transition in pentaerythritol (PET) is reported. The changes in the IR spectra with increasing and decreasing pressure have been followed up to a maximum pressure of ≈11GPa. We observe several changes in the spectra including splitting of modes and sudden change in the slope of the frequency vs. pressure curve at about 4.7 GPa. The transition has been found to be completely reversible. We interpret these changes in terms of a symmetry lowering phase transition.

Related Topics
Physical Sciences and Engineering Physics and Astronomy Atomic and Molecular Physics, and Optics
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