Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
178622 | Electrochemistry Communications | 2016 | 4 Pages |
•An aqueous electrolyte with an electrochemical stability window of 3 V has been achieved.•2 V couples of metal acetylacetonates have been tested in 10 m 1-butyl-3-methylimidazolium chloride aqueous electrolytes.•Reversible Zn2 +/Zn and Ce4 +/Ce3 + redox reactions have been demonstrated in a flow battery with a 2 V cell voltage.
Aqueous redox flow batteries with high cell voltages represent a promising approach for low-cost, high safety and high energy density applications. However, water breakdown is a major concern because it limits cell voltage. For the first time, we report the use of a highly concentrated aqueous ionic liquid electrolyte, 1-butyl-3-methylimidazolium chloride (BMImCl)-H2O, in an aqueous flow battery operating with a broad electrochemical stability window of 3 V. The proof-of-concept was demonstrated using 2 V redox couples of metal acetylacetonates and a hybrid Zn/Ce flow battery.