Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
1790082 | Journal of Crystal Growth | 2015 | 6 Pages |
•High quality zirconate pyrochlore crystals were grown by the floating zone method.•The growths were performed in a four-mirror xenon arc lamp optical image furnace.•The crystals have been characterized using X-ray diffraction techniques.•The structure of Ln2Zr2O7Ln2Zr2O7 (Ln=La,Nd,Sm) corresponds to the pyrochlore type.•Gd2Zr2O7Gd2Zr2O7 crystal boule was obtained in the defect-fluorite form.
The geometrical frustration occurring in the crystal lattice of pyrochlore oxides of the type A2B2O7A2B2O7 (where A=Rare Earth, B =Mo, Sn, Ti, Zr) leads to exotic magnetic properties of these materials. The present study focuses on a new class of frustrated magnets, the lanthanide zirconates. Large, high quality single-crystals of the rare-earth zirconium oxides, Ln2Zr2O7Ln2Zr2O7 (where Ln=La, Nd, Sm, and Gd), have been grown by the floating zone technique, using a high power xenon arc lamp furnace. The crystals have been characterized and tested for their quality using X-ray diffraction techniques.