Article ID Journal Published Year Pages File Type
1792268 Journal of Crystal Growth 2011 5 Pages PDF
Abstract

One dimensional (Mn, Li) co-doped ZnO nanorods have been prepared using electrodeposition method at constant current mode. Room temperature ferromagnetism and ferroelectricity were found coexisted in the co-doped ZnO nanorods and the underlying mechanism were discussed. The origin of the ferroelectric behavior could be explained on the basis of the ionic radii difference between the Zn2+ (0.74 Å) and the dopants ions while the ferromagnetism can be explained by a bound magnetic polaron mode and influenced by oxygen vacancies. Electron microscopy results show that the nanorod is straight with a diameter of about 80–100 nm and the density of nanorods arrays is increased when the MnCl2 concentrations increase from 0.01 to 0.02 mol/L. X-ray diffraction results confirm that the ZnO nanorods arrays are polycrystalline structure and with a (0 0 2) preferential orientation.

► One dimensional (Mn, Li) co-doped ZnO nanorods have been prepared using electrodeposition method at constant current mode. ► Room temperature ferromagnetism and ferroelectricity were found coexisted in the co-doped ZnO nanorods. ► The origin of the ferroelectric behavior could be explained on the basis of the ionic radii difference between the Zn2+ and the dopants ions. ► The ferromagnetism can be explained by a bound magnetic polaron mode and influenced by oxygen vacancies.

Related Topics
Physical Sciences and Engineering Physics and Astronomy Condensed Matter Physics
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