Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
1798417 | Journal of Magnetism and Magnetic Materials | 2016 | 5 Pages |
•CoPd granular nanolayers show perpendicular magnetic anisotropy.•Three magnetic phases are detected: hard-ferro, soft-ferro and superparamagnetism.•The nanoparticles have Co-core and CoPd alloy shell morphology.
Multilayers of bimetallic CoPd alloyed and assembled nanoparticles, prepared by room temperature sequential sputtering deposition on amorphous alumina, were studied by means of high-resolution transmission electron microscopy, x-ray diffraction, SQUID-based magnetometry and x-ray magnetic circular dichroism. Alloying between Co and Pd in these nanoparticles gives rise to a high perpendicular magnetic anisotropy. Their magnetic properties are temperature dependent: at low temperature, the multilayers are ferromagnetic with a high coercive field; at intermediate temperature the behavior is of a soft-ferromagnet, and at higher temperature, the perpendicular magnetic anisotropy in the nanoparticles disappears. The magnetic orbital moment to spin moment ratio is enhanced compared with Co bare nanoparticles and Co fcc bulk.