Magnetic study of CaMn0.96Mo0.04O3, canting vs. phase separation

CaMn0.96Mo0.04O3 is an example of Mn4+ rich perovskite manganites, which exhibits a net ferromagnetic component at low temperature, observed by dc magnetization and ac susceptibility. To characterize the magnetic state of this compound, neutron powder diffraction was carried out in the 2–400 K temperature range, showing that it is necessary to use three components (ferromagnetic and G- and A-type antiferromagnetic) to describe it. This particular state is in agreement with the unusual magnetic behaviour observed by macroscopic measurements and is compared to the one observed for manganites with similar Mn valence but obtained by A-site substitution.