Article ID Journal Published Year Pages File Type
1803219 Journal of Magnetism and Magnetic Materials 2009 4 Pages PDF
Abstract

We have studied anomalous peaks observed in magnetocaloric −ΔS(T) curves for systems that undergo first-order magnetostructural transitions. The origin of those peaks, which can exceed the conventional magnetic limit, R ln(2J+1), is discussed on thermodynamic bases by introducing an additional-exchange contribution (due to exchange constant variation arising from magnetostructural transition). We also applied a semiphenomenological model to include this additional-exchange contribution in Gd5Si2Ge2- and MnAs-based systems, obtaining excellent results for the observed magnetocaloric effect.

Related Topics
Physical Sciences and Engineering Physics and Astronomy Condensed Matter Physics
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