Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
1804864 | Journal of Magnetism and Magnetic Materials | 2007 | 8 Pages |
Abstract
The structural transformation from the metastable, disordered TbCu7-type SmCo7 structure to the equilibrium, ordered Th2Zn17-type Sm2Co17 structure was revealed by X-ray diffraction analysis using Rietveld refinement. The magnetic properties depended strongly on the stage of the transformation, as the coercivity depended on the annealing temperature. The as-solidified alloys in the TbCu7-type structure exhibited coercivity as high as 7.85Â kOe, which increased to greater than 9Â kOe after heat treatment. The magnetization processes were also strongly influenced by the structural state. Initially it was dominated by nucleation processes, which gave way to domain wall pinning-controlled magnetization processes with the development of the Sm2Co17 structure. Transmission electron microscopy revealed the development of antiphase domains during heat treatment, which apparently served as the domain-wall pinning sites during magnetization reversal.
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Authors
S. Aich, J.E. Shield,