Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
1811403 | Physica B: Condensed Matter | 2011 | 8 Pages |
Abstract
The electrical properties and the mechanism of conduction of the simultaneously substituted La0.7âxYxBa0.3Mn1âxFexO3 perovskite (0â¤xâ¤0.30) have been studied. The insertion of Y3+ and Fe3+ ions in the parent compound La0.7Ba0.3MnO3 leads to an increase of the resistivity. The undoped sample (x=0) shows a metallic behavior, which can be fitted by the relation Ï(T)=Ï0+Ï2T2+Ï4.5T4.5, indicating the importance of electron-magnon scattering effects in this material. All the other samples (xâ¥0.10) are semiconductors throughout the studied temperature range (80-290 K). Several models have been used to fit their temperature-dependent resistivity: thermal activation, adiabatic nearest-neighbor hopping of small polarons (Holstein theory) and variable range hopping (VRH) models. The fits show that the electronic transport in semiconducting La0.7âxYxBa0.3Mn1âxFexO3 is well described and dominated by the VRH mechanism, for which the hopping distance (a) grows with increasing Fe3+ doping, thus increasing the average hopping energy W.
Related Topics
Physical Sciences and Engineering
Physics and Astronomy
Condensed Matter Physics
Authors
Sonia Ben Abdelkhalek, Nabil Kallel, Sami Kallel, Thierry Guizouarn, Octavio Peña, Mohamed Oumezzine,