Article ID Journal Published Year Pages File Type
1811628 Physica B: Condensed Matter 2011 5 Pages PDF
Abstract

A series of Eu3+ doped BaLa2ZnO5 was prepared by a Pechini-type sol–gel method. The effect of Eu3+ concentration on the structure and the luminescent properties of the samples BaLa2−xEuxZnO5 were investigated by powder X-ray diffraction (XRD) and photoluminescence (PL) spectra. The sample adopts the tetragonal or orthorhombic structure as the Eu3+ concentration reaches below 1.2 or over 1.6, respectively. The sample is a mixture of tetragonal and orthorhombic phases as the contents of dopants lie between 1.2 and 1.6. The phosphor offers the strongest red light as content of Eu3+ is 0.4. In addition, the crystallization processes of the complex precursors were examined by simultaneous thermogravimetry and differential thermal analysis (TG–DTA), and also the optimal heating temperature was investigated.

Research highlights► Red emitting phosphor BaLa2ZnO5:Eu3+ was prepared by a Pechini-type sol–gel method. ► The sample BaLa2−xEuxZnO5 adopts the tetragonal or orthorhombic structures as the Eu3+ concentration is below 1.2 or over 1.6, respectively. ► Optimal heating temperature and concentration are determined.

Related Topics
Physical Sciences and Engineering Physics and Astronomy Condensed Matter Physics
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