Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
1813594 | Physica B: Condensed Matter | 2009 | 4 Pages |
Abstract
We study charge disproportionation in few quasi-two-dimensional BEDT-TTF-based compounds by following the temperature dependence of a charge-sensitive vibration ν27(B1u) of BEDT-TTF molecule. While in a charge ordered insulator θ-(BEDT-TTF)2RbZn(SCN)4 a difference between charge on the lattice sites is as high as 0.6e, a small charge disproportionation of 0.15-0.2e is found in two metallic compounds that become superconducting at low temperatures βâ³-(BEDT-TTF)2SF5CH2CF2SO3 and β-(EDT-TTF)4[Hg3I8](1-x). In contrast to these, a pure metallic βâ³-(BEDT-TTF)2SO3CHFSF5 does not show any presence of charge disproportionation. This study suggests a correlation between a slight charge disproportionation in the metallic state and superconductivity.
Related Topics
Physical Sciences and Engineering
Physics and Astronomy
Condensed Matter Physics
Authors
Natalia Drichko, Stefan Kaiser, Yaxiu Sun, Conrad Clauss, Martin Dressel, Hatsumi Mori, John Schlueter, Elena I. Zhyliaeva, Svetlana A. Torunova, Rimma N. Lyubovskaya,