Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
183551 | Electrochimica Acta | 2015 | 9 Pages |
•Wrinkly surfaced gC is employed as anode material for Li ion battery.•Temperature controlled protrusions were uniformly distributed over the nanotubes.•gC shows superior performance of 373 mAh g−1 at 100 mA g−1 after 150 cycle.•Synergistic effect of defects and conductivity gives higher Li storage over MWNTs.
A 1-D monohybrid of multiwalled carbon nanotubes and graphene sheets, graphene wrapped multiwalled carbon nanotubes (gC) structure, synthesized in a template-free simple chemical vapor deposition technique without any chemical functionalization, was employed as efficient anode material for Li ion battery. Graphene nanosheets affixed to the multiwalled carbon nanotubes (MWNTs) surface by van der Waal's attraction gives a wrinkled surface to the final 1-D gC configuration. The protrusions on the surface of the tube enhances the porosity of the system and also acts as defects, enhancing lithium adsorption sites while the inner MWNT core gives high electrical conductivity, resulting enhanced electrochemical performance of 373 mAh g−1 at 100 mA g−1 current density after 150 cycles.
Graphical abstractFigure optionsDownload full-size imageDownload as PowerPoint slide