Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
1865742 | Physics Letters A | 2009 | 8 Pages |
Abstract
The self-assembled colloidal crystals with structure transitions were realized experimentally on substrates with polymer brushes. Such polymer-mediated colloidal crystals were found to experience a series of in-layer structure transitions including stable columnar, polycrystalline, mixed square-hexagonal, square, hexagonal structures when the mass ratio of colloidal particles to free polymers was adjusted from 0.125 to 10. Among these structures, a large area interfacial square structure was proved to be a body-centered tetragonal (BCT) structure in three dimensions in the polymer-mediated colloidal crystals.
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Authors
C.R. Han, J.G. Cao, L.W. Zhou, X.C. Pang, J.L. Huang, L.F. Zhang, J.P. Huang,