Article ID Journal Published Year Pages File Type
186578 Electrochimica Acta 2014 6 Pages PDF
Abstract

•The peak fitting of cyclic voltammetry provides more detailed information about electrochemical reaction.•3D nanoporous stainless steel plate was a good current collector for lithium ion battery.•MnO2 nanoflakes show an excellent electrochemical performance.

Interconnected MnO2 nanoflakes supported by 3D nanostructured stainless steel (SS) plates are prepared by a facile hydrothermal synthesis. The resultant architecture is used as binder-free anodes of lithium ion batteries. Cyclic voltammetry analysis is conducted to distinguish the reactions between lithium ions and the active material at various discharge-charge potentials. Galvanostatic battery testing shows that the representative electrode exhibits a reversible capacity up to 1387.1 mA h g−1 at a current rate of 0.2 C after 100 cycles and a capacity higher than 492.9 mA h g−1 at a rate of 5 C. Such an excellent cycling performance, better rate capability and high capacity indicate that the simply etched 3D SS plate is a promising nanostructured current collector.

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Physical Sciences and Engineering Chemical Engineering Chemical Engineering (General)
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