| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 187351 | Electrochimica Acta | 2013 | 4 Pages |
Abstract
A Nb–Ti–Ni hydrogen permeable alloy was synthesized as a powder using the OS process, which involves the simultaneous reduction of a mixture of Nb, Ti, and Ni oxides by Ca that is generated from molten CaCl2 via electrolysis. The mechanism confirmed that a BCC-(Nb, Ti) phase easily formed at an early stage of the reaction followed by the generation of a B2-TiNi phase from the lower oxides such as NbO and Ti2O. The oxygen content of the synthesized alloy decreased significantly to 0.27 mass% with increased electric charge. The three elements were uniformly distributed at the macroscopic level.
Related Topics
Physical Sciences and Engineering
Chemical Engineering
Chemical Engineering (General)
Authors
Ryunosuke Enmei, Tatsuya Kikuchi, Ryosuke O. Suzuki,