Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
1876897 | Applied Radiation and Isotopes | 2009 | 4 Pages |
Abstract
Conjugates of bacteriochlorin p and chlorin e6 with cobalt bis(dicarbollide) anion [3,3’-Co(1,2-C2B9H11)2]− were synthesized using different synthetic approaches. The boronated bacteriochlorin p was prepared by reaction of bacteriochlorin N-amino cycloimide with, bis(dicarbollide)-based carboxylic acid. The boronated chlorin e6 conjugates were obtained by both “click reaction” of containing alkyne group chlorine with azide derivative of cobaltacarborane and reaction of chorin-based amines with cyclic oxonium derivative of cobalt bis(dicarbollide).
Related Topics
Physical Sciences and Engineering
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Radiation
Authors
V.I. Bregadze, I.B. Sivaev, I.A. Lobanova, R.A. Titeev, D.I. Brittal, M.A. Grin, A.F. Mironov,