Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
187712 | Electrochimica Acta | 2013 | 7 Pages |
Abstract
The electroreduction of nitrogen species in alkaline medium was performed on platinum nanoparticles (1–2 nm) with metal loadings of 5 and 10 wt% Pt, synthesized by the chemical carbonyl route. The electrochemically active surface analysis evidences that the real surface area is concomitant to the Pt-loading in the support. The electrochemical analysis put in evidence that nitrite ions were reduced from −0.6 to −0.78 V and the charge transfer step is attributed to the NO2−/NO redox couple. The Tafel slope analysis confirms that from Ep to −0.78 V the reduction of NO occurs via an ECE mechanism. An analysis of Nicholson–Shain schemes and NO-saturated in solution verified these results.
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Authors
L.A. Estudillo-Wong, G. Santillán-Díaz, E.M. Arce-Estrada, N. Alonso-Vante, A. Manzo-Robledo,