Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
1878760 | Applied Radiation and Isotopes | 2013 | 5 Pages |
•This paper used 222Rn as a tracer for estimating a NAPL-contaminated groundwater site.•222Rn partition coefficient in water and some NAPLs was examined by batch experiment.•The partition coefficient of gasoline, diesel, PCE, TCE was acquired from the regression results.•Rn shows a strong affinity to NAPLs, so semi-quantitative results should be possible.•TCE contaminated 54 groundwater samples in Wonju city, Republic of Korea, was analyzed using 222Rn tracer.
The naturally occurring radioisotope 222Rn was used as a partitioning tracer to evaluate the presence and amount of a non-aqueous phase liquid (NAPL) in an aquifer. The batch experiment results of a diesel contaminated soil showed that the emanation rate of 222Rn decreased to 31%, relative to a background rate. Batch experiment results of water contaminated by gasoline, diesel, PCE and TCE were similar. A field study to examine TCE contamination was conducted using 54 groundwater samples in Wonju city, Republic of Korea. Estimates of TCE contamination ranged from <0.001 mg/L to 14.3 mg/L, and 222Rn concentrations ranged from 1.89 Bq/L to 444. Results of 222Rn analysis showed that TCE contamination was mainly restricted to an asphalt laboratory area and that the 222Rn values of a NAPL-contaminated aquifer were correlated with TCE analytical results.