Article ID Journal Published Year Pages File Type
187988 Electrochimica Acta 2013 9 Pages PDF
Abstract

This study demonstrates that platinum–ruthenium (PtRu) nanoclusters decorated on a composite consisting of graphene sheets (GS) and carbon nanotubes (CNTs), denoted as PtRu/GS-CNT, show highly electrocatalytic activity for methanol oxidation with excellent carbon monoxide (CO) tolerance. Herein, restacking of individual GS is effectively inhibited by introducing one-dimensional CNTs to form a 3-D porous microstructure. From the SEM image, CNTs act as useful nanospacers for diminishing the face-to-face aggregation of GS. This 3-D porous structure exposes extensive surface area for evenly depositing PtRu nanoclusters and facilitates the electrolyte/reactant diffusion, leading to the highly catalytic performances of resultant materials. The voltammetric forward peak current density to the reverse peak current density for PtRu/GS-CNT (If/Ib = 6.33) is much higher than that of commercial catalyst, PtRu/Vulcan XC-72 (If/Ib = 1.33), revealing the synergistic effects between GS and CNT on enhancing electrochemical activities of PtRu nanoclusters for the methanol oxidation and the carbon monoxide (CO) tolerance. Therefore, the 3-D GS-CNT nanocomposite is a promising support material for dispersing noble metal catalysts in the fuel cell applications.

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Physical Sciences and Engineering Chemical Engineering Chemical Engineering (General)
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