| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 188431 | Electrochimica Acta | 2012 | 6 Pages |
A novel biomimetic membrane made of conducting polymer (CP) film with dispersed biological ligands (BL) is described. Adenosine diphosphate (ADP), which serves as BL, is invited as a dopant into the CP matrix formed by poly(ethylene 3,4 dioxythiophene) (PEDOT) during electropolymerization. The PEDOT–ADP films are characterized with scanning electron microscopy (SEM), energy dispersive X-ray (EDAX) and atomic force microscopy (AFM). Films are made sensitive to divalent cations (Ca2+ or Mg2+) with an optimized electrochemical oxidation and soaking processes. Resulting close-to-Nernstian potentiometric slopes are observed. Transitory potentials for the PEDOT–ADP films are studied with open-circuit measurements. Distinctively different responses for the bulk concentration changes of Ca2+ or Mg2+ ions are ascribed to a competitive ion-exchange process on the ADP sites.
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