Article ID Journal Published Year Pages File Type
188734 Electrochimica Acta 2012 8 Pages PDF
Abstract

The temperature distribution and shape evolution during electrochemical machining (ECM) are the result of a large number of intertwined physical processes. Electrolyte flow, electrical conduction, ion transport, electrochemical reactions, heat generation and heat transfer strongly influence one another, making modeling and numerical simulation of ECM a very challenging procedure. In part I [1], a temperature dependent multi-ion transport and reaction model (MITReM) is put forward which considers mass transfer as a consequence of diffusion, convection and migration, combined with the electroneutrality condition and linearized temperature dependent polarization relations at the electrode–electrolyte interface. The flow field is calculated using the incompressible laminar Navier–Stokes equations for viscous flow. The local temperature is obtained by solving internal energy balance, enabling the use of temperature dependent expressions for several physical properties such as the ion diffusion coefficients and electrolyte viscosity. In this second part, the temperature dependent MITReM is used to simulate ECM of stainless steel in aqueous NaNO3 electrolyte solution. The effects of temperature, electrode thermal conduction, reaction heat generation, electrolyte flow and water depletion are investigated. A comparison is made between the temperature dependent potential model and MITReM.

Related Topics
Physical Sciences and Engineering Chemical Engineering Chemical Engineering (General)
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