Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
193530 | Electrochimica Acta | 2007 | 9 Pages |
Abstract
The electropolymerization of o-anisidine leads to the formation of a polymer which is in the same time strongly oxidized and charged in a large potential range: the poly-o-methoxyaniline (POMA). The POMA Raman features are strongly different from the polyaniline (PANI) ones; in particular a new band, absent from the PANI spectrum, prevails in a large potential range. The nature of the polymer structures obtained in function of the polarization potential is discussed from their Raman spectra. A new polymeric configuration of the oxidized/charged rings is therefore described.
Related Topics
Physical Sciences and Engineering
Chemical Engineering
Chemical Engineering (General)
Authors
M.C. Bernard, A. Hugot-Le Goff, H. Arkoub, B. Saïdani,