Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
195959 | Electrochimica Acta | 2005 | 6 Pages |
Abstract
The complexation of simple anions (F− and Cl−) to different neutral species, anion-coordinating agents, has been studied using electronic structure calculations. The obtained changes in the equilibrium constants for salt dissolution reactions in different typical electrolyte systems are reported. In addition the lithium ion affinities of the obtained anionic complexes have been calculated. Using the present results we discuss strategies for future usage of anion complexing agents and make recommendations of salt and agent combinations for better lithium battery electrolyte performance.
Related Topics
Physical Sciences and Engineering
Chemical Engineering
Chemical Engineering (General)
Authors
Patrik Johansson, Per Jacobsson,