Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
196152 | Electrochimica Acta | 2006 | 6 Pages |
Abstract
Electrochemical oxidation of catechols (1a–d) has been studied in the presence of N,N-dimethylethylendiamine (3) as a nucleophile in aqueous solutions, using cyclic voltammetry, constant-current coulometry and controlled-potential coulometry. The results indicate that the quinones derived from catechols (2a–d) participate in Michael addition reactions with N,N′-dimethylethylendiamine (3) via the ECECE mechanism to form the corresponding quinoxalinedione derivatives (6a–c).
Related Topics
Physical Sciences and Engineering
Chemical Engineering
Chemical Engineering (General)
Authors
Davood Habibi, Davood Nematollahi, Zahede Seyyed Al-Hoseini, Sara Dehdashtian,