Article ID Journal Published Year Pages File Type
196408 Electrochimica Acta 2007 6 Pages PDF
Abstract

Abnormal “polymer-in-salt” conduction behavior is observed in a solid electrolyte composed of lithium iodide (LiI) and 3-hydroxypropionitrile (HPN). Based on comprehensive investigations by X-ray diffraction (XRD) and Raman and infrared spectroscopy, this abnormal conduction behavior is attributed to the formation of new ionic associates [Lim+In−]⋯NC (m > n) and the reinforced hydrogen bonding of I⋯HO in the electrolyte at high LiI concentrations.

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Physical Sciences and Engineering Chemical Engineering Chemical Engineering (General)
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