Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
196408 | Electrochimica Acta | 2007 | 6 Pages |
Abstract
Abnormal “polymer-in-salt” conduction behavior is observed in a solid electrolyte composed of lithium iodide (LiI) and 3-hydroxypropionitrile (HPN). Based on comprehensive investigations by X-ray diffraction (XRD) and Raman and infrared spectroscopy, this abnormal conduction behavior is attributed to the formation of new ionic associates [Lim+In−]⋯NC (m > n) and the reinforced hydrogen bonding of I⋯HO in the electrolyte at high LiI concentrations.
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Physical Sciences and Engineering
Chemical Engineering
Chemical Engineering (General)
Authors
H.X. Wang, Z.X. Wang, H. Li, Q.B. Meng, L.Q. Chen,