Electrocrystallisation of tantalum in molten fluoride media

The electrochemical nucleation of tantalum in molten alkaline fluoride media is investigated using chronoamperometry in the 670–750 °C temperature range to optimize the operating conditions for preparing tantalum coatings for anode materials. Chronoamperometric results show that the electrodeposition process involves progressive nucleation with diffusion-controlled growth of the nuclei, which was confirmed by scanning electron microscopy. The influence of the temperature and the overpotential on the nucleation site densities is considered.Once the deposit has been obtained, plotting the roughness of the tantalum coatings as a function of the current densities reveals a minimum at about 80 mA/cm2. This minimum is considered by the authors as a consequence of the progressive nucleation.