Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
202401 | Fluid Phase Equilibria | 2013 | 7 Pages |
Abstract
Henry's law constants and infinite dilution activity coefficients were measured for toluene, 1-butanol, anisole, 1,2-difluorobenzene, 4-bromotoluene, 1,2,3-trichlorobenzene, and 2,4-dichlorotoluene in water using the inert gas stripping method at ambient pressure (approximately 86.2 kPa) and at temperatures between 281.15 K and 323.15 K. Fugacity ratios, required to determine infinite dilution activity coefficients for the solid solutes, were calculated from literature values for the heat of fusion and the liquid and solid heat capacities. Chemicals were chosen based on missing or conflicting data from the literature.
Related Topics
Physical Sciences and Engineering
Chemical Engineering
Chemical Engineering (General)
Authors
Sarah A. Brockbank, Jenna L. Russon, Neil F. Giles, Richard L. Rowley, W. Vincent Wilding,