Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
203050 | Fluid Phase Equilibria | 2010 | 5 Pages |
Abstract
A flow-mixing isothermal microcalorimeter has been used to determine the excess molar enthalpies for five binary systems of diethyl malonate+ (1-butanol, 2-methyl-1-propanol, 1-pentanol, n-heptane, and ethyl acetate) at T= (288.2, 298.2, 313.2, 328.2, 338.2, and 348.2 K) and p = 101.3 kPa. The HmE values increase with increasing temperature. The experimental data have been correlated by the Redlich–Kister equation and two local composition models (NRTL and UNIQUAC).
Related Topics
Physical Sciences and Engineering
Chemical Engineering
Chemical Engineering (General)
Authors
Yihe Wang, Hui Gao, Weidong Yan,