Article ID Journal Published Year Pages File Type
203050 Fluid Phase Equilibria 2010 5 Pages PDF
Abstract

A flow-mixing isothermal microcalorimeter has been used to determine the excess molar enthalpies for five binary systems of diethyl malonate+ (1-butanol, 2-methyl-1-propanol, 1-pentanol, n-heptane, and ethyl acetate) at T= (288.2, 298.2, 313.2, 328.2, 338.2, and 348.2 K) and p = 101.3 kPa. The HmE values increase with increasing temperature. The experimental data have been correlated by the Redlich–Kister equation and two local composition models (NRTL and UNIQUAC).

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Physical Sciences and Engineering Chemical Engineering Chemical Engineering (General)
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